Hydrogen Donors in Anatase TiO2

Tunable polaronic conduction in anatase TiO2.

Oxygen vacancies created in anatase TiO(2) by UV photons (80-130 eV) provide an effective electron-doping mechanism and induce a hitherto unobserved dispersive metallic state. Angle resolved photoemission reveals that the quasiparticles are large polarons. These results indicate that anatase can be tuned from an insulator to a polaron gas to a weakly correlated metal as a function of doping and...

High-pressure polymorphs of anatase TiO2

Band alignment of rutile and anatase TiO2

The most widely used oxide for photocatalytic applications owing to its low cost and high activity is TiO2. The discovery of the photolysis of water on the surface of TiO2 in 19721 launched four decades of intensive research into the underlying chemical and physical processes involved2–5. Despite much collected evidence, a thoroughly convincing explanation of why mixed-phase samples of anatase ...

Anatase TiO2 and mixed M-Anatase TiO2 (M = CeO2 or ZrO2) nano powder: Synthesis and characterization

Pure Anatase Titania (TiO2), mixed 1.0 wt.% Cerium-Anatase Titania (1.0 wt.%CeO2-TiO2), and mixed 1.0 wt.% Zirconia-Anatase Titania (1.0 wt.%ZrO2-TiO2) nano powders were synthesized by co-precipitation method and characterized using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area analysis, UV-Vis diffuse reflectance spect...

High-Pressure Study of Anatase TiO2

We report resistivity and thermo-electric power measurements of the anatase phase of TiO2 under pressure up to 2.3 GPa. Despite its transparent appearance, the single crystal of anatase exhibits a metallic-like resistivity above 60 K, at all pressures. The rather high value of the thermo-electric power at room temperature points to complex transport mechanism in this phase.